Fe-Catalyzed insertion of fluoromethylcarbenes generated from sulfonium salts into X–H bonds (X = Si, C, P)
Fe-Catalyzed insertion of fluoromethylcarbenes generated from sulfonium salts into X–H bonds (X = Si, C, P)
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DOI：
10.1039/c7qo00430c
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发表时间：
2017-09
影响因子：
5.4
通讯作者：
Y. Duan;Jin‐Hong Lin;Ji-Chang Xiao;Yucheng Gu
中科院分区：
文献类型：
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作者：
Y. Duan;Jin‐Hong Lin;Ji-Chang Xiao;Yucheng Gu
The Fe-catalyzed insertion of fluoromethylcarbenes including trifluoromethylcarbene and difluoromethylcarbene generated in situ from sulfonium salts (Ph2S+CH2CF3−OTf and Ph2S+CH2CF2H −OTf) into X–H (X = Si, C and P) bonds is described. The insertion of both carbenes into the Si–H bond occurred smoothly, and trifluoromethylcarbene could also insert into C–H and P–H bonds.
