Living Ring-Opening Polymerization of O-Carboxyanhydrides: The Search for Catalysts
Living Ring-Opening Polymerization of O-Carboxyanhydrides: The Search for Catalysts
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DOI：
10.3389/fchem.2018.00641
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发表时间：
2018-12
影响因子：
5.5
通讯作者：
Yongliang Zhong;R. Tong
中科院分区：
文献类型：
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作者：
Yongliang Zhong;R. Tong
邻羧基氢化物（OCAs）的开环聚合（ROP）可以合成可生物降解的聚α-羟基酸。目前已经开发了许多催化剂来控制OCAs的活性聚合。在这里，我们回顾了OCA的基本原理，OCA的ROP催化剂的理想特性和重要属性，以及已经开发的具体例子。
Biodegradable poly(α-hydroxy acids) can be synthesized by means of ring-opening polymerization (ROP) of O-carboxyanhydrides (OCAs). Numerous catalysts have been developed to control the living polymerization of OCAs. Here we review the rationale for the use of OCA, the desirable features for and important attributes of catalysts for the ROP of OCAs, and specific examples that have been developed.