Thermodynamic Insights on the Feasibility of Homogeneous Batch Extractive Distillation. 4. Azeotropic Mixtures with Intermediate Boiling Entrainer
Thermodynamic Insights on the Feasibility of Homogeneous Batch Extractive Distillation. 4. Azeotropic Mixtures with Intermediate Boiling Entrainer
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DOI：
10.1021/ie2019432
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发表时间：
2012-04
影响因子：
4.2
通讯作者：
I. Rodríguez-Donis;V. Gerbaud;X. Joulia
中科院分区：
文献类型：
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作者：
I. Rodríguez-Donis;V. Gerbaud;X. Joulia
本文展示了单挥发性和不分布线位置以及残渣曲线分析的知识如何帮助评估使用中间沸点夹带剂对共沸混合物进行间歇萃取精馏或汽提蒸馏的可行性。我们考虑五种最低沸点（minT）共沸混合物AB与夹带剂E，即丙酮-庚烷与苯、甲醇-甲苯与三乙胺、乙酸甲酯-环己烷与四氯化碳、二氯甲烷-乙醇与丙酮、以及乙酸乙酯-庚烷与苯；和一种最大沸点 (maxT) 共沸混合物，即氯仿-乙酸乙酯与 2-氯丁烷、异丁基氯、溴丙烷或溴氯甲烷。所有三元图 A–B–E 都属于 1.0-1b 类，所有三种可能的单波动性 αAB、αBE 和 αAE 以及单分布线 KA、KB 和 KE 都可以存在。应用 Rodriguez-Donis 等人的一般可行性标准。 （工业化学研究 2009, 48 (7), 3544−3559）...
This paper shows how knowledge of the univolatility and unidistribution line location and residue curve analysis help to assess the feasibility of batch extractive rectifying or stripping distillation of azeotropic mixtures by using an intermediate boiling entrainer. We consider five minimum boiling (minT) azeotropic mixtures AB with entrainer E, namely, acetone–heptane with benzene, methanol–toluene with triethylamine, methyl acetate–cyclohexane with carbon tetrachloride, dichloromethane–ethanol with acetone, and ethyl acetate–heptane with benzene; and one maximum boiling (maxT) azeotropic mixture, namely, chloroform–ethyl acetate with either 2-chlorobutane, isobutylchloride, bromopropane, or bromochloromethane. All ternary diagrams A–B–E belong to the 1.0-1b class, for which all three possible univolatility, αAB, αBE, and αAE, and unidistribution lines, KA, KB, and KE can exist. With application of the general feasibility criterion of Rodriguez-Donis et al. (Ind. Eng. Chem. Res. 2009, 48 (7), 3544−3559)...