Diamondoid Phosphines – Selective Phosphorylation of Nanodiamonds[1]
Diamondoid Phosphines – Selective Phosphorylation of Nanodiamonds[1]
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DOI：
10.1002/adsc.200900774
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发表时间：
2010-03
影响因子：
5.4
通讯作者：
Hartmut Schwertfeger;Mareike M. Machuy;Christian Würtele;J. Dahl;R. Carlson;P. Schreiner
中科院分区：
文献类型：
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作者：
Hartmut Schwertfeger;Mareike M. Machuy;Christian Würtele;J. Dahl;R. Carlson;P. Schreiner
通过在类似弗瑞德-克来福特条件下与三氯化磷反应，将金刚烷（纳米金刚石）二金刚烷和三金刚烷选择性地转化为二有机次膦酰氯。随后用三氯硅烷还原二金刚石基次膦酰氯，得到迄今未知的相应二金刚石基膦。这些类金刚石次膦酰氯和膦由于其非凡的刚性和空间体积，作为有机元素和配位化学的起始材料具有很大的用途。
The diamondoids (nanodiamonds) diamantane and triamantane were selectively converted into diorganophosphinic acid chlorides by reacting them with phosphorus trichloride under Friedel-Crafts-like conditions. The di-diamondoid phosphinic acid chlorides were subsequently reduced with trichlorosilane to give the hitherto unknown corresponding di-diamondoid phosphines. These diamondoid phosphinic acid chlorides and phosphines are of great utility as starting materials in organo-element and coordination chemistry due to their extraordinary rigidity and steric bulk.