Cesium(I)-mediated 3-D superstructures by one-pot self-organization of hydrogen-bonded nickel complexes.
Cesium(I)-mediated 3-D superstructures by one-pot self-organization of hydrogen-bonded nickel complexes.
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DOI：
10.1021/ic010331s
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发表时间：
2001-10
影响因子：
4.6
通讯作者：
M. Tadokoro;T. Shiomi;K. Isobe;K. Nakasuji
中科院分区：
文献类型：
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作者：
M. Tadokoro;T. Shiomi;K. Isobe;K. Nakasuji
用[Ni(Hbim)3]-1构筑块自组织形成了{Cs[Ni(Hbim)3]}n(A)和{[Ni(Hbim)3]2Cs(NnPr4)·MeOH}n(B)两种超结构，它们同时使用了HBIM-1的配位几何构型和三个分子间位置。A和B的网络结构分别为二维蜂窝状和三维双螺旋结构。它们的形成是由于[Ni(Hbim)3]-1与Cs+离子的强相互作用所致。
Two superstructures of {Cs[Ni(Hbim)3]}n (A) and {[Ni(Hbim)3]2 Cs(NnPr4)·MeOH}n (B) were formed by a self-organization with [Ni(Hbim)3]-1 building blocks, which use both coordination geometry and three intermolecular sites of Hbim-1. The networks of A and B have indicated 2-D honeycomb sheets and 3-D double-helical structure, respectively. Their formations are owed to the existence of a Cs+ ion due to a strong interaction with the [Ni(Hbim)3]-1.