Iron polypyridyl catalysts assembled on metal oxide semiconductors for photocatalytic hydrogen generation
Iron polypyridyl catalysts assembled on metal oxide semiconductors for photocatalytic hydrogen generation
复制标题
金属氧化物半导体上组装的铁聚吡啶催化剂用于光催化制氢
DOI：
10.1039/c8cc00453f
复制
发表时间：
2018
影响因子：
4.9
通讯作者：
McNamara, W. R.
中科院分区：
文献类型：
--
作者：
Race, N. A.;Zhang, W.;Screen, M. E.;Barden, B. A.;McNamara, W. R.
最近报道了一系列与荧光素和三乙胺配对的铁(III)配合物，它们对光催化产氢具有活性。在这里，我们报道了一种固定在二氧化钛和钛酸锶上的铁(III)络合物，其活性明显高于均相体系，在31小时内实现了高达7800次的转化率。
A series of Fe(III) complexes was recently reported that are active for photocatalytic hydrogen generation when paired with fluorescein and triethylamine. Herein we report an Fe(III) complex immobilized on TiO2 and SrTiO3 that is significantly more active than the homogeneous system, achieving up to 7800 turnovers in 31 hours.