Iron‐Catalyzed Dehydrogenation of Alcohols Using Benzoquinones as Electrochemically Regenerable Mediators
Iron‐Catalyzed Dehydrogenation of Alcohols Using Benzoquinones as Electrochemically Regenerable Mediators
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使用苯醌作为电化学可再生介体铁催化醇脱氢
DOI：
10.1002/ejoc.202200149
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发表时间：
2022
影响因子：
2.8
通讯作者：
Jones, William D.
中科院分区：
文献类型：
--
作者：
Ritz, Mikhaila D.;Jones, William D.
开发了以苯二酚为电化学可再生介质的高效、原子经济的铁催化醇类脱氢反应。在这项工作中，铁环戊二酮络合物被电化学研究，并测试其在该体系中的有效性。这种方法随后扩展到各种仲醇和伯醇，提供了中等到良好的产品产率。
The efficient and atom economical iron‐catalyzed dehydrogenation of alcohols using benzoquinones as electrochemically regenerable mediators has been developed. In this work, an iron cyclopentadienone complex was electrochemically studied and tested for its effectiveness within this system. This methodology was then extended to various secondary and primary alcohols affording moderate to good yields of product.