Engineering inorganic interfaces using molecular nanolayers
Engineering inorganic interfaces using molecular nanolayers
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DOI：
10.1063/5.0146122
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发表时间：
2023-06
影响因子：
4
通讯作者：
G. Ramanath;Collin Rowe;G. Sharma;V. Venkataramani;J. Alauzun;R. Sundararaman;P. Keblinski;D. Sangiova
中科院分区：
文献类型：
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作者：
G. Ramanath;Collin Rowe;G. Sharma;V. Venkataramani;J. Alauzun;R. Sundararaman;P. Keblinski;D. Sangiova
过去 20 年界面科学的进展表明，可以在无机界面使用分子纳米层 (MNL) 来研究新兴现象并增强各种界面特性。在这里，我们捕获了 MNL 如何诱导多重增强并调整多种界面特性的重要方面，包括化学稳定性、断裂能、热和电传输以及电子结构。描述和讨论了这一新兴领域成熟所需解决的关键挑战。 MNL 诱导的界面工程为设计具有高界面分数的有机-无机杂化纳米材料开辟了诱人的机会，其中性能主要由 MNL 诱导的应用界面效应决定。
Advances in interface science over the last 20 years have demonstrated the use of molecular nanolayers (MNLs) at inorganic interfaces to access emergent phenomena and enhance a variety of interfacial properties. Here, we capture important aspects of how a MNL can induce multifold enhancements and tune multiple interfacial properties, including chemical stability, fracture energy, thermal and electrical transport, and electronic structure. Key challenges that need to be addressed for the maturation of this emerging field are described and discussed. MNL-induced interfacial engineering has opened up attractive opportunities for designing organic–inorganic hybrid nanomaterials with high interface fractions, where properties are determined predominantly by MNL-induced interfacial effects for applications.