A Co-Crystal Strategy to Tune the Supramolecular Patterns and Luminescent Properties: Ten Well-Designed Salts Assembled by Arenedisulfonic Acid with Diverse Diamines
A Co-Crystal Strategy to Tune the Supramolecular Patterns and Luminescent Properties: Ten Well-Designed Salts Assembled by Arenedisulfonic Acid with Diverse Diamines
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DOI：
10.1021/cg3004855
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发表时间：
2012-05
影响因子：
3.8
通讯作者：
Zhaopeng Deng;L. Huo;Hui Zhao;Shan Gao
中科院分区：
文献类型：
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作者：
Zhaopeng Deng;L. Huo;Hui Zhao;Shan Gao
十盐组装用肼arenedisulfonic酸,灵活的脂肪族二元胺,刚性和半刚性的芳香族二元胺,即(H2HA) 2 +·(NDS) 2 - (1), (H2EDA) 2 +·(NDS) 2 - (2), (H2PDA) 2 +·(NDS) 2 - (3), (H2BTDA) 2 +·(NDS) 2 - (4), (H2BDMA) 2 +·(NDS) 2 - 2·H2O (5), 2 (o-HBDA) +·(NDS) 2 - (6), (m-H2BDA) 2 +·(NDS) 2 - (7), (H2MBDA) 2 + 2 -··(NDS) 3 H2O(8)、(H2SDA) 2 + 2 -··(NDS)水(9)和2 (HSDA) +·(NDS) 2 -·H2O (10) (H2NDS = 1, 5-naphthalenedisulfonic酸、公顷=肼,EDA = 1, 2-ethanediamine, PDA = 1, 3-propanediamine,构造了BTDA = 1,4-丁二胺，BDMA = 1,3-苯二胺，o-BDA = 1,2-苯二胺，m-BDA = 1,3-苯二胺，MBDA = 4-甲基-1,3-苯二胺，SDA = 4,4 ' -磺酰二胺)，并通过元素分析、红外、热重分析、磷光、粉末和单晶x射线衍射等手段对其进行了表征。结构分析表明，二胺的性质可以通过不同的非共价键相互作用有效地影响盐的最终结构。
Ten salts assembled by arenedisulfonic acid with hydrazine, flexible aliphatic diamines, rigid and semirigid aromatic diamines, namely, (H2HA)2+·(NDS)2– (1), (H2EDA)2+·(NDS)2– (2), (H2PDA)2+·(NDS)2– (3), (H2BTDA)2+·(NDS)2– (4), (H2BDMA)2+·(NDS)2–·2H2O (5), 2(o-HBDA)+·(NDS)2– (6), (m-H2BDA)2+·(NDS)2– (7), (H2MBDA)2+·(NDS)2–·3H2O (8), (H2SDA)2+·(NDS)2–·H2O (9), and 2(HSDA)+·(NDS)2–·H2O (10) (H2NDS = 1,5-naphthalenedisulfonic acid, HA = hydrazine, EDA = 1,2-ethanediamine, PDA = 1,3-propanediamine, BTDA = 1,4-butanediamine, BDMA = 1,3-benzenedimethanamine, o-BDA = 1,2-benzenediamine, m-BDA = 1,3-benzenediamine, MBDA = 4-methyl-1,3-benzenediamine, SDA = 4,4′-sulfonyldiamiline), have been constructed and characterized by elemental analysis, infrared, thermogravimetric analysis, phospholuminescence, and powder and single-crystal X-ray diffraction. Structural analyses indicate that the nature of the diamines can effectively influence the final structures of the salts through diverse noncovalent bonding interactio...