Generation of Linear Coordination Polymers of catena-[Diaqua-(μ-pyrazine-2,6-dicarboxylato-N,O,O‘-μ-N‘)copper(II) via in Situ Hydro(solvo)thermal Decarboxylation of Pyrazine-2,3,5,6-tetracarboxylic Acid
Generation of Linear Coordination Polymers of catena-[Diaqua-(μ-pyrazine-2,6-dicarboxylato-N,O,O‘-μ-N‘)copper(II) via in Situ Hydro(solvo)thermal Decarboxylation of Pyrazine-2,3,5,6-tetracarboxylic Acid
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DOI：
10.1021/cg050621
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发表时间：
2006-02
影响因子：
3.8
通讯作者：
M. Yigit;Y. Wang;A. B. Moulton;J. MacDonald
中科院分区：
文献类型：
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作者：
M. Yigit;Y. Wang;A. B. Moulton;J. MacDonald
吡嗪-2，3，5，6-四羧酸与Cu（II）在水（溶剂）热条件下的反应导致两个羧基原位脱羧形成吡嗪-2，6-二羧酸。该配体与Cu（II）配位生成链状-[二水-（μ-吡嗪-2，6-二羧酸根-N，O，O '-μ-N'）铜（II）]的线性配位聚合物。
Reaction of pyrazine-2,3,5,6-tetracarboxylic acid with Cu(II) under hydro(solvo)thermal conditions causes in situ decarboxylation of two carboxyl groups to form pyrazine-2,6-dicarboxylic acid. Coordination of Cu(II) by this ligand generates linear coordination polymers of catena-[diaqua-(μ-pyrazine-2,6-dicarboxylato-N,O,O‘-μ-N‘)copper(II).