SYNTHESIS AND MESOMORPHIC PROPERTIES OF FERROELECTRIC LIQUID-CRYSTALS BEARING TRANS 4-ALKOXYCYCLOHEXYLPYRIMIDINES

SYNTHESIS AND MESOMORPHIC PROPERTIES OF FERROELECTRIC LIQUID-CRYSTALS BEARING TRANS 4-ALKOXYCYCLOHEXYLPYRIMIDINES
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DOI:
10.1080/10587259408047176
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发表时间:
1994-01-01
影响因子:
--
通讯作者:
MURAYAMA, A
MURAYAMA, A
中科院分区:
其他
文献类型:
--
作者:
SUGITA, S;TODA, S;MURAYAMA, A

文献摘要

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合成了一系列手性反式-4-烷氧基环己基嘧啶类化合物,并用DSC和偏光显微镜研究了它们的液晶性质。结果发现,反式-1,4-二取代环己烷环的存在下,强烈促进SB相的形成,似乎抑制手性近晶C(Sc*)相的形成。
A homologous series of chiral trans-4-alkoxycyclohexylpyrimidines were synthesized and their mesomorphic properties were evaluated with a DSC and a polarizing microscope. It was found that the presence of a trans-1,4-disubstituted cyclohexane ring strongly promoted the formation of the SB phase and seems to suppress the formation of the chiral smectic C (Sc*) phase.