Indium Triiodide Catalyzed Reductive Functionalization of Amides via the Single-Stage Treatment of Hydrosilanes and Organosilicon Nucleophiles
Indium Triiodide Catalyzed Reductive Functionalization of Amides via the Single-Stage Treatment of Hydrosilanes and Organosilicon Nucleophiles
复制标题
三碘化铟通过氢硅烷和有机硅亲核试剂的一步处理催化酰胺的还原官能化
作者：
Yoshihiro Inamoto;Yuta Kaga;Yoshihiro Nishimoto;Makoto Yasuda;Akio Baba
三碘化铟催化的N-磺酰胺与含氢硅烷的单级级联反应和两类有机硅亲核试剂如氰硅烷和烯醇化硅选择性地促进脱氧功能化反应，分别得到α-氰基胺和β-氨基羰基化合物.
The indium triiodide catalyzed single-stage cascade reaction ofN-sulfonyl amides with hydrosilanes and two types of organosilicon nucleophiles such as silyl cyanide and silyl enolates selectively promoted deoxygenative functionalization to give α-cyanoamines and β-aminocarbonyl compounds, respectively.