Patterned nitroxide polymer brushes for thin-film cathodes in organic radical batteries.
Patterned nitroxide polymer brushes for thin-film cathodes in organic radical batteries.
复制标题
DOI：
10.1039/c0cc02442b
复制
发表时间：
2011-01
影响因子：
4.9
通讯作者：
Yu-Hsuan Wang;Miao‐Ken Hung;Chun-Hao Lin;Hsiao-Chien Lin;J. Lee
中科院分区：
文献类型：
--
作者：
Yu-Hsuan Wang;Miao‐Ken Hung;Chun-Hao Lin;Hsiao-Chien Lin;J. Lee
通过表面引发的原子转移自由基聚合和微接触印刷，在柔性导电基底上共价图案化氮氧聚合物刷。作为有机自由基电池的阴极，氮氧聚合物刷防止氮氧聚合物溶解到电解质溶剂中，这提高了电池的循环寿命性能。
Nitroxide polymer brushes were covalently patterned on flexible conducting substrates via surface-initiated atom transfer radical polymerization and microcontact printing. As a cathode of organic radical batteries, the nitroxide polymer brushes prevent the nitroxide polymer from dissolving into electrolyte solvents, which improves the cycle-life performance of batteries.