A large interconnecting network within hybrid MEH-PPV/TiO2 nanorod photovoltaic devices
A large interconnecting network within hybrid MEH-PPV/TiO2 nanorod photovoltaic devices
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DOI：
10.1088/0957-4484/17/21/017
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发表时间：
2006-11
期刊：
影响因子：
3.5
通讯作者：
Tsung-Wei Zeng;Y. Lin;Hsi-Hsing Lo;Chun-Wei Chen;Cheng-Hsuan Chen;S. Liou;Hongrui Huang;W. Su
中科院分区：
文献类型：
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作者：
Tsung-Wei Zeng;Y. Lin;Hsi-Hsing Lo;Chun-Wei Chen;Cheng-Hsuan Chen;S. Liou;Hongrui Huang;W. Su
研究了基于TiO 2纳米棒和聚[2-甲氧基-5-（2′-乙基己氧基）-1，4-亚苯基亚乙烯基]（MEH-PPV）的杂化光伏器件。我们使用二氧化钛纳米棒作为电子受体和传导途径。在这里，我们描述了如何开发一个大的互连网络内的光伏器件制造的插入一层的二氧化钛纳米棒之间的MEH-PPV：二氧化钛纳米棒混合活性层和铝电极。大的互连网络的形成提供了与电极的更好的连接性，与没有TiO 2纳米棒层的参考器件相比，导致外部量子效率提高了2.5倍。在565 nm波长下，功率转换效率为2.2%，在430 nm波长下，最大外量子效率为24%。在空气质量1.5的照明下获得0.49%的功率转换效率。
This is a study of hybrid photovoltaic devices based on TiO2 nanorods and poly[2-methoxy-5-(2′-ethyl-hexyloxy)-1,4-phenylene vinylene] (MEH-PPV). We use TiO2 nanorods as the electron acceptors and conduction pathways. Here we describe how to develop a large interconnecting network within the photovoltaic device fabricated by inserting a layer of TiO2 nanorods between the MEH-PPV:TiO2 nanorod hybrid active layer and the aluminium electrode. The formation of a large interconnecting network provides better connectivity to the electrode, leading to a 2.5-fold improvement in external quantum efficiency as compared to the reference device without the TiO2 nanorod layer. A power conversion efficiency of 2.2% under illumination at 565 nm and a maximum external quantum efficiency of 24% at 430 nm are achieved. A power conversion efficiency of 0.49% is obtained under Air Mass 1.5 illumination.