Crystallization induced block copolymer decoration on carbon nanotubes
Crystallization induced block copolymer decoration on carbon nanotubes
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碳纳米管上的结晶诱导嵌段共聚物修饰
DOI:
10.1016/j.carbon.2009.12.059
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发表时间:
2010-04
期刊:
影响因子:
10.9
通讯作者:
Ye, Xiong-ying
中科院分区:
文献类型:
--
作者:
Wang, Wei-ru;Xie, Xu-ming;Ye, Xiong-ying
A unique noncovalent means to decorate block copolymers on carbon nanotubes (CNTs) using a controlled polymer crystallization method is presented. Transmission electron microscope observation and electron diffraction result demonstrated the surface functionalization of CNTs with a crystalline–noncrystalline triblock copolymer poly(vinylcyclohexane)-b-poly(ethylene)-b-poly(vinylcyclohexane) (PVCH-PE-PVCH), forming a novel nano-hybrid epitaxial brush structure, which consists of a central CNT and disc-shaped folded-chain lamellae of PE blocks with random coils of amorphous PVCH blocks surrounding them.
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