Crystallization induced block copolymer decoration on carbon nanotubes

Crystallization induced block copolymer decoration on carbon nanotubes
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碳纳米管上的结晶诱导嵌段共聚物修饰

DOI:
10.1016/j.carbon.2009.12.059
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发表时间:
2010-04
期刊:
影响因子:
10.9
通讯作者:
Ye, Xiong-ying
Ye, Xiong-ying
中科院分区:
材料科学2区
文献类型:
--
作者:
Wang, Wei-ru;Xie, Xu-ming;Ye, Xiong-ying

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提出了一种利用可控聚合物结晶方法在碳纳米管上修饰嵌段共聚物的独特非共价方法。透射电子显微镜观察和电子衍射结果表明,结晶-非结晶三嵌段共聚物聚乙烯环己烷-b-聚乙烯-b-聚乙烯环己烷(PVCH-PE-PVCH)对CNTs进行表面功能化,形成了一种新型的纳米杂化外延刷结构,该结构由CNT和PE嵌段组成的盘状折叠链片层以及无定形PVCH嵌段的无规卷曲组成。
A unique noncovalent means to decorate block copolymers on carbon nanotubes (CNTs) using a controlled polymer crystallization method is presented. Transmission electron microscope observation and electron diffraction result demonstrated the surface functionalization of CNTs with a crystalline–noncrystalline triblock copolymer poly(vinylcyclohexane)-b-poly(ethylene)-b-poly(vinylcyclohexane) (PVCH-PE-PVCH), forming a novel nano-hybrid epitaxial brush structure, which consists of a central CNT and disc-shaped folded-chain lamellae of PE blocks with random coils of amorphous PVCH blocks surrounding them.
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