Formation of Interconnected Macropores in Sm2+-doped Silicate Glasses through Phase Separation: Fabrication of Photosensitive and Dielectrically Disordered Materials

Formation of Interconnected Macropores in Sm2+-doped Silicate Glasses through Phase Separation: Fabrication of Photosensitive and Dielectrically Disordered Materials
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通过相分离在 Sm2 掺杂硅酸盐玻璃中形成互连大孔:光敏和介电无序材料的制造

DOI:
10.1246/cl.2004.1120
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发表时间:
2004
期刊:
影响因子:
1.6
通讯作者:
K. Hirao
K. Hirao
中科院分区:
化学4区
文献类型:
--
作者:
K. Fujita;S. Murai;Y. Ohashi;K. Nakanishi;K. Hirao

文献摘要

相似文献

利用相分离现象,通过两种不同的方法制备了具有互连大孔的Sm 2 +掺杂硅酸盐玻璃,一种是热处理下宏观均匀的熔融淬冷玻璃的液-液相分离,另一种是烷氧基衍生的溶胶-凝胶体系中聚合诱导的相分离.采用溶胶-凝胶法成功地制备了Sm 2 +掺杂的大孔硅酸盐玻璃。
Fabrication of Sm 2 + -doped silicate glasses possessing interconnected macropores has been attempted via two different procedures utilizing a phase-separation phenomenon; one includes liquid-liquid phase separation of macroscopically uniform melt-quenched glasses under heat treatment, and the other polymerization-induced phase separation in alkoxy-derived sol-gel systems. Macroporous silicate glasses doped with Sm 2 + can be successfully prepared via the sol-gel method.