A 3.5-nm coordination nanotube.
A 3.5-nm coordination nanotube.
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DOI：
10.1021/ja047048n
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发表时间：
2004-08
影响因子：
15
通讯作者：
Takumi Yamaguchi;S. Tashiro;Masahide Tominaga;M. Kawano;T. Ozeki;M. Fujita
中科院分区：
文献类型：
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作者：
Takumi Yamaguchi;S. Tashiro;Masahide Tominaga;M. Kawano;T. Ozeki;M. Fujita
一个3.5-nm的配位纳米管自组装从12个Pd（II）离子和4个带状配体的援助下的3.0-nm的模板。通过单晶X射线分析明确地确定了这种管状结构。通过24个Pd（II）-吡啶相互作用协同维持，即使当模板被移除时，框架也是动力学稳定的。当然，空管能够结合空腔中的其他分子。
A 3.5-nm coordination nanotube was self-assembled from 12 Pd(II) ions and four tape-shaped ligands with the aid of a 3.0-nm template. This tubular structure was unambiguously determined by the single-crystal X-ray analysis. Being cooperatively sustained by 24 Pd(II)-pyridine interactions, the framework was kinetically stable even when the template was removed. The empty tube was, of course, capable of binding other molecules in the cavity.