Addition Reactions of Cation Radicals of Nitroalkanes to Olefinic Compounds by the Use of Manganese(III) 2-Pyridinecarboxylate
Addition Reactions of Cation Radicals of Nitroalkanes to Olefinic Compounds by the Use of Manganese(III) 2-Pyridinecarboxylate
复制标题
2-吡啶甲酸锰(III)对硝基烷烃阳离子自由基与烯烃化合物的加成反应
DOI：
10.1246/cl.1991.423
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发表时间：
1991
影响因子：
1.6
通讯作者：
T. Okauchi
中科院分区：
文献类型：
--
作者：
K. Narasaka*;K. Iwakura;T. Okauchi
酸性硝基烷烃的甲硅烷基衍生物与烯烃如甲硅烷基烯醇醚、乙烯基硫醚和烯胺通过2-吡啶羧酸锰（III）氧化反应选择性地得到分子间加成产物。
Silyl derivatives of aci-nitroalkanes react with olefins such as silyl enol ether, vinyl sulfide, and enamine by oxidation with manganese(III) 2-pyridinecarboxylate to give the intermolecular addition products selectively.