Phosphine-free synthesis of heavy Co2+- and Fe2+-doped Cu2SnSe3 nanocrystals by virtue of alkylthiol-assistant Se powder dissolution
Phosphine-free synthesis of heavy Co2+- and Fe2+-doped Cu2SnSe3 nanocrystals by virtue of alkylthiol-assistant Se powder dissolution
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DOI:
10.1039/c3ta01391j
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发表时间:
2013-01
影响因子:
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通讯作者:
Yi Liu;Dong Yao;Shiyu Yao;J. Zhao;Hao Zhang;Wenjing Tian;Bai Yang
中科院分区:
文献类型:
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作者:
Yi Liu;Dong Yao;Shiyu Yao;J. Zhao;Hao Zhang;Wenjing Tian;Bai Yang
We demonstrate a phosphine-free method to synthesize heavy Co2+- and Fe2+-doped Cu2SnSe3 nanocrystals (NCs) by virtue of alkylthiol-assistant Se powder dissolution in organic solvents. The as-synthesized NCs exhibit a promising increase in photocurrent under AM1.5 illumination. Since the current method is simple and convenient it holds promise for facilitating the progress in photovoltaic devices from Cu-based NCs.