Facile preparation of allylzinc species from allylboronates and zinc amide via a boron-to-zinc exchange process and their reactions with carbonyl compounds, imines and hydrazones
Facile preparation of allylzinc species from allylboronates and zinc amide via a boron-to-zinc exchange process and their reactions with carbonyl compounds, imines and hydrazones
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DOI：
10.1039/c2cc34340a
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发表时间：
2012-01-01
影响因子：
4.9
通讯作者：
Kobayashi, Shu
中科院分区：
文献类型：
--
作者：
Cui, Yi;Yamashita, Yasuhiro;Kobayashi, Shu
发现了烯丙基硼酸酯和锌酰胺容易形成烯丙基锌物种。硼到锌的交换过程顺利进行，得到了相应的烯丙基锌酰胺，并成功地应用于亲电体烯丙化反应。还报道了使用手性锌酰胺进行不对称催化的方法。
Facile formation of allylzinc species from allylboronate and zinc amide was discovered. The boron-to-zinc exchange process occurred smoothly to afford the corresponding allylzinc amides, which were successfully employed in catalytic allylation reactions with electrophiles. Asymmetric catalysis using a chiral zinc amide is also reported.