Development of β-keto 1,3-dithianes as versatile intermediates for organic synthesis
Development of β-keto 1,3-dithianes as versatile intermediates for organic synthesis
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DOI:
10.1039/b208982c
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发表时间:
2003-01-07
影响因子:
3.2
通讯作者:
Ley, SV
中科院分区:
文献类型:
--
作者:
Gaunt, MJ;Sneddon, HF;Ley, SV
beta-Keto 1,3-dithianes can be generated by the double conjugate addition of dithiols to propargylic ketones, esters and aldehydes in excellent yields. As masked 1,3-dicarbonyl systems these substrates can be converted to a range of functionalised oxygen-containing heterocycles that can be used in natural product synthesis.