Stereoselective Synthesis of (E)-(Trisubstituted alkenyl)borinic Esters: Stereochemistry Reversed by Ligand in the Palladium-Catalyzed Reaction of Alkynylborates with Aryl Halides
Stereoselective Synthesis of (E)-(Trisubstituted alkenyl)borinic Esters: Stereochemistry Reversed by Ligand in the Palladium-Catalyzed Reaction of Alkynylborates with Aryl Halides
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DOI：
10.1021/ol902278q
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发表时间：
2009-12-03
期刊：
影响因子：
5.2
通讯作者：
Murakami, Masahiro
中科院分区：
文献类型：
--
作者：
Ishida, Naoki;Shimamoto, Yasuhiro;Murakami, Masahiro
在钯催化下，炔基硼酸酯与卤代芳烃反应，立体选择性地得到了（E）-（三取代烯基）-9-BBN，其中两个不同的芳基以反式方式安装在一起。
The palladium-catalyzed reaction of alkynylborates with aryl halides stereoselectively gave (E)-(trisubstituted alkenyl)-9-BBNs, In which two different aryl groups were Installed trans to each other.