MOLECULAR THEORY OF RUBBER ELASTICITY
MOLECULAR THEORY OF RUBBER ELASTICITY
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DOI：
10.1016/0032-3861(79)90268-4
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发表时间：
1985-01-01
期刊：
影响因子：
2.8
通讯作者：
FLORY, PJ
中科院分区：
文献类型：
--
作者：
FLORY, PJ
对橡胶弹性理论进行了回顾和比较。主要差异集中在网络连接位置和宏观应变之间的联系上。人们认为，周围链条对结点的限制是导致实验偏离理想化“幻影”网络理论的原因。讨论了支持利用这一假说开发的理论的实验证据。
Theories of rubber elasticity are reviewed and compared. Principal differences centre on the connection between the locations of network junctions and the macroscopic strain. Constraints on junctions imposed by surrounding chains have been postulated to be responsible for departures of experiments from the theory for idealized ‘phantom’ networks. Experimental evidence in support of theory developed using this hypothesis is discussed.