Effect of thermal history on helium diffusion and solubility in vitreous B2O3 and sodium borate glasses

Effect of thermal history on helium diffusion and solubility in vitreous B2O3 and sodium borate glasses
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热史对 B2O3 和硼酸钠玻璃中氦扩散和溶解度的影响

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发表时间:
1973
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影响因子:
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通讯作者:
J. Shelby
J. Shelby
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文献类型:
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作者:
J. Shelby

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Helium diffusivity and solubility in vitreous B2O3 and sodium borate glasses (0–7 mol% Na2O) can be decreased by as much as 30% by thermal annealing. It is concluded that this decrease is due to thermally induced volume relaxation. Since these measurements can be made while the sample is being annealed, they can be used to determine the time dependence of the volume relaxation process. The relaxation time at 182°C for vitreous B2O3 as determined from the time dependence of the helium diffusion coefficient is approximately 6 × 104 sec.