SYNTHESIS OF PHENANTHROINDOLIZIDINES .2. SYNTHESIS OF (+/-)-TYLOCREBRINE, (+/-)-TYLOPHORINE, (+/-)-ANTOFINE, AND (+/-)-2,3-DI ETHOXYPHENANTHROINDOLIZIDINE
SYNTHESIS OF PHENANTHROINDOLIZIDINES .2. SYNTHESIS OF (+/-)-TYLOCREBRINE, (+/-)-TYLOPHORINE, (+/-)-ANTOFINE, AND (+/-)-2,3-DI ETHOXYPHENANTHROINDOLIZIDINE
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DOI：
10.1071/ch9702503
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发表时间：
1970-01-01
影响因子：
1.1
通讯作者：
GELLERT, E
中科院分区：
文献类型：
--
作者：
CHAUNCY, B;GELLERT, E
本文报道了菲咯吲哚里西定生物碱的外消旋体泰洛克瑞滨、阿佛林和安妥芬以及以前未知的2，3-二甲氧基菲咯吲哚里西定的新合成方法。n.m.r.的一些特点。讨论了最终产物和某些合成中间体的光谱。
A new synthesis of the racemic forms of the phenanthroindolizidine alkaloids, tylocrebine, tylophorine, and antofine, together with the previously unknown 2,3-dimethoxyphenanthroindolizidine, is described. Some features of the n.m.r. spectra of the final products and certain of the synthetic intermediates are discussed.