Synthesis and structural characterization of amorphous nano-sized SiBONC ceramic powders via polymer pyrolysis
Synthesis and structural characterization of amorphous nano-sized SiBONC ceramic powders via polymer pyrolysis
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DOI：
10.1016/j.jnoncrysol.2006.12.018
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发表时间：
2007-03
影响因子：
3.5
通讯作者：
F. Li;G. Wen;H. Bai;Liangcheng Song
中科院分区：
文献类型：
--
作者：
F. Li;G. Wen;H. Bai;Liangcheng Song
SiBONC ceramic powders have been prepared via a polymer pyrolysis route using silicon tetrachloride (SiCl4), benzaldehyde (PhCHO), boron trichloride (BCl3) and aniline (PhNH2) as starting materials. Fourier transform infrared spectra (FT-IR), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), and transmission electron microscopy (TEM) were performed to investigate the structural characteristics of the polymer precursor and the ceramic powders. The SiBONC ceramic powders in spherical shape with a mean diameter of 50nm are amorphous and composed of B–N, Si–O, Si–C, and SiONxgroups. The SiBONC ceramic powders were sintered at 1700°C to a dense material which still remained amorphous.
