An NMR study of dioxouranium(VI)-CMPO complex
An NMR study of dioxouranium(VI)-CMPO complex
复制标题
二氧铀(VI)-CMPO配合物的核磁共振研究
DOI：
10.1016/0925-8388(93)90320-m
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发表时间：
1993
影响因子：
6.2
通讯作者：
C. Miyake
中科院分区：
文献类型：
--
作者：
J. Sakamoto;C. Miyake
合成了UO 22 + CMPO配合物，经元素分析确定其为UO 2（NO3）2·CMPO，并通过自旋退耦和C-H COSY对13 C信号进行了归属，包括与31 P的偶合常数。1H、13 C和31 P NMR和IR谱表明配合物中形成了六元环<$U <$O <$C <$P <$O <$。
UO22+CMPO complex was prepared and identified to be UO2(NO3)2·CMPO by elemental analysis.13C signals were assigned by spin decoupling and C-H COSY, including coupling constants with31P. The observed1H,13C and31P NMR and IR spectra show the formation of a six-membered ring UOCCPO in the complex.