Sequential and highly stereoselective intermolecular radical additions of 2,3-cis-disubstituted 1,1-dibromo- and 1-bromocyclopropanes to electron-deficient olefins

Sequential and highly stereoselective intermolecular radical additions of 2,3-cis-disubstituted 1,1-dibromo- and 1-bromocyclopropanes to electron-deficient olefins
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DOI:
10.1016/0040-4039(96)00156-6
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发表时间:
1996-03-11
影响因子:
1.8
通讯作者:
Nishii, Y
Nishii, Y
中科院分区:
化学4区
文献类型:
--
作者:
Tanabe, Y;Wakimura, K;Nishii, Y

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Novel and sequential intermolecular radical additions of 2,3-cis-disubstituted 1,1-dibromo- and 1-bromocyclopropanes to electron-deficient olefins proceeded with high stereoselectivity, i.e., in an exo-face addition manner. This highly stereoselective addition was also applied to an intramolecular cyclization.