The Mackay-Type Cluster [Cu43 Al12 ](Cp*)12 : Open-Shell 67-Electron Superatom with Emerging Metal-Like Electronic Structure.
The Mackay-Type Cluster [Cu43 Al12 ](Cp*)12 : Open-Shell 67-Electron Superatom with Emerging Metal-Like Electronic Structure.
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DOI：
10.1002/anie.201806039
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发表时间：
2018-07
影响因子：
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通讯作者：
Jana Weßing;Chelladurai Ganesamoorthy;S. Kahlal;R. Marchal;C. Gemel;O. Cador;Augusto C H Da Silva;J. L. D. Da Silva;J. Saillard;R. Fischer
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文献类型：
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作者：
Jana Weßing;Chelladurai Ganesamoorthy;S. Kahlal;R. Marchal;C. Gemel;O. Cador;Augusto C H Da Silva;J. L. D. Da Silva;J. Saillard;R. Fischer
The paramagnetic cluster [Cu43 Al12 ](Cp*)12 was obtained from the reaction of [CuMes]5 and [AlCp*]4 (Cp*=η5 -C5 Me5 ; Mes=mesityl). This all-hydrocarbon ligand-stabilized M55 magic atom-number cluster features a Mackay-type nested icosahedral structure. Its open-shell 67-electron superatom configuration is unique. Three unpaired electrons occupy weakly antibonding jellium states. The situation prefigures the formation of a conduction band, which is in line with the measured temperature-independent magnetism. Steric protection by twelve Cp* ligands suppresses the intrinsic polyradicalar reactivity of the Cu43 Al12 core.
