Generation of β-keto radicals from cyclopropanols catalyzed by AgNO3
Generation of β-keto radicals from cyclopropanols catalyzed by AgNO3
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DOI：
10.1246/cl.2006.18
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发表时间：
2006-01-05
影响因子：
1.6
通讯作者：
Narasaka, K
中科院分区：
文献类型：
--
作者：
Chiba, S;Cao, ZY;Narasaka, K
在吡啶存在的情况下，通过催化量的AgNO3和(NH4)(2)S2O8作为复氧化剂，从环丙醇生成各种β-酮自由基。因此，生成的β-酮基与烯烃反应生成加成产物。
Various Beta-keto radicals are generated from cyclopropanols by treatment with a catalytic amount of AgNO3 and (NH4)(2)S2O8 as a reoxidant in the presence of pyridine. Thus, generated beta-keto radicals react with alkenes to yield addition products.