Kinetics of Exchange Reactions
Kinetics of Exchange Reactions
复制标题
交换反应动力学
作者：
H. Mckay
通过绘制反应物或生成物的浓度随时间变化的曲线形状，通常可以用来得出反应速率随浓度变化的信息，特别是反应的顺序。在同位素交换反应的情况下，即使假设同位素具有相同的化学性质，这在原则上也是不可能的。到目前为止，这个相当有趣的结果似乎还没有被记录在案。
THE shape of the curve obtained by plotting the concentration of a reactant or product against the time can in general be used to yield information about the way the rate of the reaction depends on concentration, in particular about its order. In the case of isotopic exchange reactions this is not possible even in principle, supposing the isotopes to have identical chemical properties. This rather amusing result does not appear to have been placed on record hitherto.