Polymer Chains in Confined Spaces and Flow-Injection Problems: Some Remarks

Polymer Chains in Confined Spaces and Flow-Injection Problems: Some Remarks
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DOI:
10.1021/ma0514424
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发表时间:
2005-06
期刊:
影响因子:
5.5
通讯作者:
T. Sakaue;E. Raphael
T. Sakaue;E. Raphael
中科院分区:
化学1区
文献类型:
--
作者:
T. Sakaue;E. Raphael

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We revisit the classical problem of the behavior of an isolated linear polymer chain in confined spaces, introducing the distinction between two different confinement regimes (the weak and the strong confinement regimes, respectively). We then discuss some recent experimental findings concerning the partitioning of individual polymers into protein pores. We also generalize our study to the case of branched polymers, and study the flow-injection properties of such objects into nanoscopic pores, for which the strong confinement regime plays an important role.