Präparationsprinzipien mikroporöser Materialien: Vom building block zum hierarchisch aufgebauten porösen System

Präparationsprinzipien mikroporöser Materialien: Vom building block zum hierarchisch aufgebauten porösen System
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微孔材料的制备原理:从积木到分级结构多孔系统

DOI:
10.1002/cite.201500163
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发表时间:
2016
影响因子:
1.9
通讯作者:
M. Hartmann
M. Hartmann
中科院分区:
工程技术4区
文献类型:
--
作者:
W. Schwieger;M. Klumpp;S. A. Al-Thabaiti;M. Hartmann

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微孔材料是众所周知的,并且由于它们在吸附和催化过程中的独特性质,在关于例如靶向材料合成和在新过程中的潜在应用的研究中也仍然具有越来越大的兴趣。虽然,它是他们的微孔性,这是在吸附和催化的杰出性能的首要责任性质,这也是它的小孔径,阻碍了这样的过程的动力学。因此,这种差异是目前层次多孔材料发展的主要驱动力。本文简要介绍了微孔材料及其结构单元的基本概念和制备原理,并对近年来的研究进展进行了综述,重点介绍了多级孔沸石的研究进展。
Microporous materials are well known and due to their unique properties in sorptive and catalytic processes also of still growing interest in research with regards to, eg, targeted material synthesis and potential application in novel processes. Though, it is their microporosity which is in the first place the responsible property for the outstanding performance in sorption and catalysis, it is also its small pore size which thwarts the kinetic of such processes. This discrepancy is therefore the main driving force for the ongoing development of hierarchically porous materials. This article gives a basic description of microporous materials and their building blocks in general as well as the underlying principles of their preparation and additionally gives a review on the field of recent developments with special focus on hierarchically porous zeolites.
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