The three dimensional solubility parameter - key to paint component affinities: I. Solvents, plasticizers, polymers, and resins

The three dimensional solubility parameter - key to paint component affinities: I. Solvents, plasticizers, polymers, and resins
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DOI:
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发表时间:
1967-02
期刊:
Journal of Biomaterials Science, Polymer Edition
影响因子:
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通讯作者:
C. Hansen
C. Hansen
中科院分区:
其他
文献类型:
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作者:
C. Hansen

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提出了溶解度参数是由氢键、极性和分散组分组成的矢量的概念,并成功地应用于33种聚合物和树脂在90种溶剂和10种增塑剂中的溶解度预测。溶剂和增塑剂可以定位为三维体系中的点,当绘制溶解度数据时,聚合物和树脂的溶解度区域被发现。在400多个案例中,发现混合物中不相互作用的溶剂相互作用的准确率超过95%。--CAL
The concept that the solubility parameter is a vector composed of hydrogen bonding, polar, and dispersion components is proposed and applied with success to prediction of the solubility of 33 polymers and resins in 90 solvents and 10 plasticizers. Solvents and plasticizers can be located as points in a three dimensional system, and regions of solubility are found for polymers and resins when solubility data are plotted. Non-interacting solvents which in a mixture become interacting have been found with better than 95% accuracy in over 400 cases. -- CAL