Metallosupramolecular coordination polyelectrolytes investigated by Mössbauer spectroscopy

Metallosupramolecular coordination polyelectrolytes investigated by Mössbauer spectroscopy
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穆斯堡尔光谱研究金属超分子配位聚电解质

DOI:
10.1007/s10751-006-9309-2
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发表时间:
2005
影响因子:
--
通讯作者:
A. Thünemann
A. Thünemann
中科院分区:
--
文献类型:
--
作者:
A. Lindner;M. Mentzel;F. Renz;D.G. Kurth;A. Thünemann

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用穆斯堡尔谱研究了基于刚性和柔性双取代双吡啶配体和Fe(II)离子的金属超分子配位聚电解质(MEPEs)。我们展示了磨削产生的机械应力对MEPE结构的影响,以及MEPE通过重结晶进行自我修复的能力。
Metallosupramolecular coordination polyelectrolytes (MEPEs) based on rigid and flexible ditopic bis-terpyridine ligands and Fe(II) ions are investigated by Mössbauer spectroscopy. We demonstrate the influence of mechanical stress induced by grinding on the structure of MEPE as well as the ability of MEPE to self-repair through recrystallisation.