Etheric bimesogens and the twist-bend nematic phase

Etheric bimesogens and the twist-bend nematic phase
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DOI:
10.1080/02678292.2015.1091095
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发表时间:
2016-01-01
期刊:
影响因子:
2.2
通讯作者:
Goodby, John W.
Goodby, John W.
中科院分区:
化学3区
文献类型:
--
作者:
Mandle, Richard J.;Voll, Constantin C. A.;Goodby, John W.

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尽管分子结构和扭曲-弯曲双相的发生之间的关系被部分理解,很少有人知道这些关系是如何表现为醚连接的双介晶。在这篇文章中,我们报告了几种新型的醚连接的双介晶,表现出N-TB相,并探讨这些材料的热性能如何在很大程度上取决于两个芳香族,碳环或刚性环单元之间的角度。
Despite the relationship between molecular structure and the occurrence of the twist-bend nematic phase being partially understood, very little is known about how these relationships are manifested for ether-linked bimesogens. In this article, we report several novel ether-linked bimesogens that exhibit the N-TB phase and explore how the thermal properties of these materials are largely governed by the angle between the two aromatic, carbocyclic or rigid cyclic units.