Dual Raman features of double coaxial carbon nanotubes with N-doped and B-doped multiwalls

Dual Raman features of double coaxial carbon nanotubes with N-doped and B-doped multiwalls
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DOI:
10.1021/nl051779j
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发表时间:
2005-12-01
期刊:
影响因子:
10.8
通讯作者:
Kyotani, T
Kyotani, T
中科院分区:
材料科学1区
文献类型:
--
作者:
Yang, QH;Hou, PX;Kyotani, T

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氮(N)掺杂和硼(B)掺杂的双同轴碳纳米管多壁具有复合拉曼特征,不仅来自外部N掺杂层,还来自内部B掺杂层。N和B掺杂均导致构成纳米管壁的sp(2)碳的特征D带和G带的显著位移,但方式不同。无论N或B掺杂与否,碳纳米管的G带的下移与电阻率的降低有关。
Double coaxial carbon nanotubes with nitrogen (N)-doped and boron (B)-doped multiwalls possess composite Raman characteristics, originating not only from the outer N-doped but also from inner B-doped layers. Both N and B dopings result in substantial shifts of the characteristic D band and G band of sp(2) carbon constituting nanotube walls but in different ways. The downshift of the G band is correlated with the decreases of electrical resistivity of carbon nanotubes regardless of N or B doping.