Synthesis and characterization of an infinite sheet of metal-alkyl bonds: unfolding the elusive structure of an unsolvated alkali-metal trisalkylmagnesiate
Synthesis and characterization of an infinite sheet of metal-alkyl bonds: unfolding the elusive structure of an unsolvated alkali-metal trisalkylmagnesiate
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DOI：
10.1039/c0cc02164d
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发表时间：
2011-01-01
影响因子：
4.9
通讯作者：
Russo, Luca
中科院分区：
文献类型：
--
作者：
Baillie, Sharon E.;Clegg, William;Russo, Luca
对NaCH（2）SiMe（3）和Mg（CH（2）SiMe（3））（2）之间的共络合反应的研究允许分离和结构解析第一个无溶剂的碱金属烷基镁酸盐[{NaMg（CH（2）SiMe（3））（3）}（infinity）]（1）以及相关的无溶剂的烷基钠[{（NaCH（2）SiMe（3））（4）}（infinity）]（3）。
The study of co-complexation reactions between NaCH(2)SiMe(3) and Mg(CH(2)SiMe(3))(2) has allowed the isolation and structural elucidation of the first solvent-free alkali-metal alkylmagnesiate [{NaMg(CH(2)SiMe(3))(3)}(infinity)] (1) as well as the related solvent-free sodium alkyl [{(NaCH(2)SiMe(3))(4)}(infinity)] (3).