Electron-donating curved π-electronic systems that complex with buckyball
Electron-donating curved π-electronic systems that complex with buckyball
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与巴基球复合的供电子弯曲 π 电子系统
DOI：
10.1039/d2cp01575g
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发表时间：
2022
影响因子：
3.3
通讯作者：
Yasuda Nobuhiro
中科院分区：
文献类型：
--
作者：
Maeda Hiromitsu;Abiko Taichi;Haketa Yohei;Kobayashi Yoichi;Ishibashi Yukihide;Asahi Tsuyoshi;Yasuda Nobuhiro
在弯曲π-电子系统中，二吡咯基苯二氮卓类化合物得到了各种具有调制电子性质和组装行为的衍生物。富电子吡咯基弯曲π体系以氢键环六聚体的形式表现出C60络合作用，通过瞬态吸收光谱分析证实了该体系存在固态光致电子转移。
Modifications in curved π-electronic systems, dipyrrolylbenzodiazepines, resulted in various derivatives with modulated electronic properties and assembly behaviour. The electron-rich pyrrole-based curved π-system exhibited C60 complexation in the form of a hydrogen-bonding cyclic hexamer, giving rise to solid-state photo-induced electron transfer as elucidated by transient absorption spectroscopy.