A new synthetic route to metal trithiophosphonates: syntheses and structures of [(C6H11)PS3Li2).THF.TMEDA]2 and [(C6H11))PS3Mg.2THF]2.
A new synthetic route to metal trithiophosphonates: syntheses and structures of [(C6H11)PS3Li2).THF.TMEDA]2 and [(C6H11))PS3Mg.2THF]2.
复制标题
金属三硫代膦酸盐的合成新路线：[(C6H11)PS3Li2).THF.TMEDA]2和[(C6H11))PS3Mg.2THF]2的合成和结构。
作者：
Jens K. Bjernemose;R. Davies;Andrew P S Jurd;M. Martinelli;P. Raithby;Andrew J. P. White
提出了一种由伯膦、nBuLi（或nBu（2）Mg）和元素硫合成三硫代膦酸酯的新方法，并对其机理进行了研究;环己基三硫代膦酸酯的锂盐和镁盐已被充分表征，以揭示固态的二聚体，其中所有三个三硫代膦酸酯硫都参与金属键合。
A new synthesis for trithiophosphonates from primary phosphines, nBuLi (or nBu(2)Mg) and elemental sulfur is presented and its mechanism investigated; the lithium and magnesium salts of cyclohexyltrithiophosphonate have been fully characterised to reveal dimers in the solid state in which all three of the trithiophosphonate sulfurs are involved in metal bonding.