Direct enhancement of intercomponent interactions in polyrotaxane and its pronounced effects on glass state properties
Direct enhancement of intercomponent interactions in polyrotaxane and its pronounced effects on glass state properties
复制标题
聚轮烷中组分间相互作用的直接增强及其对玻璃态性能的显着影响
DOI：
10.1039/d1cc05516j
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发表时间：
2021
影响因子：
4.9
通讯作者：
Ito Kohzo
中科院分区：
文献类型：
--
作者：
Kato Kazuaki;Mizusawa Tomoki;Ohara Akihiro;Ito Kohzo
通过对聚丁二烯基聚轮烷的聚合物进行选择性改性，引入了主体环糊精和螺纹客体聚合物之间的强相互作用。组分间相互作用的变化影响了限制在玻璃态主体框架中的螺纹聚合物的流动性，从而导致不同的机械性能。
Strong interactions between the host cyclodextrin and the threading guest polymer were introduced by selective modifications to the polymer of a polybutadine-based polyrotaxane. The changes in the intercomponent interactions influenced the mobility of the threading polymer that was confined in the glassy host framework, resulting in different mechanical properties.