Synthesis and characterization of half-sandwich iridium complexes containing 2,6(7)-bis(4-pyridyl)-1,4,5,8-tetrathiafulvalene and ancillary ortho-carborane-1,2-dichalcogenolato ligands
Synthesis and characterization of half-sandwich iridium complexes containing 2,6(7)-bis(4-pyridyl)-1,4,5,8-tetrathiafulvalene and ancillary ortho-carborane-1,2-dichalcogenolato ligands
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含有 2,6(7)-双(4-吡啶基)-1,4,5,8-四硫富瓦烯和辅助邻碳硼烷-1,2-二卤代烷配体的半夹心铱配合物的合成和表征
DOI：
10.1016/j.jorganchem.2007.04.034
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发表时间：
2007-10-01
影响因子：
2.3
通讯作者：
Jin, Guo-Xin
中科院分区：
文献类型：
--
作者：
Han, Ying-Feng;Zhang, Jia-Sheng;Jin, Guo-Xin
{Cp*IrCl2}(2)(mu-2，6(7)-bis(4-pyridyl)-1，4，5，8-tetrathiafulvalene)(3)和{Cp*Ir[E2C2-(B10H10)]}(2)(mu-2，6(7)-bis(4-pyridyl)-1，4，5，8-tetrathiafulvalene)(E=S(5a)，以四硫富瓦烯(TTF)衍生物2，6-双(4-吡啶基)-1，4，5，8-四硫富瓦烯(2)为原料，与[Cp*IrCl(Mu-Cl)](2)或“拟芳香型”半夹心结构Ir络合物Cp*Ir[E2C2(B10H10)](E=S(4a)，Se(4b))在室温下反应合成了Se(Sb)。化合物(3，5a和5b)的结构经红外光谱、核磁共振光谱和元素分析确证。并通过X-射线单晶衍射法确定了2和5a的分子结构。有趣的是，无限大的隧道是通过重复5a的“弯曲碗”分子来创建的。(C)2007 Elsevier B.V.保留所有权利。
The binuclear half-sandwich iridium complexes {Cp*IrCl2}(2)(mu-2,6(7)-bis(4-pyridyl)-1,4,5,8-tetrathiafulvalene) (3) and {Cp*Ir[E2C2-(B10H10)]}(2)(mu-2,6(7)-bis(4-pyridyl)-1,4,5,8-tetrathiafulvalene) (E = S(5a), Se(Sb)) were prepared from the reaction of [Cp*IrCl(mu-Cl)](2) or the "pseudo-aromatic" half-sandwich iridium complex Cp*Ir[E2C2(B10H10)] (E = S(4a), Se(4b)) with a tetrathiafulvalene (TTF) derivative 2,6-bis(4-pyridyl)-1,4,5,8-tetrathiafulvalene (2) at room temperature. The complexes (3, 5a and 5b) have been fully characterized by IR and NMR spectroscopy, as well as elemental analysis. And the molecular structures of 2 and 5a were established through X-ray crystallography. It is interesting that infinite tunnels are created by repeating 'buckled bowl' molecules of 5a. (C) 2007 Elsevier B.V. All rights reserved.