Hydrogen Peroxide: A Key Chemical for Today's Sustainable Development
Hydrogen Peroxide: A Key Chemical for Today's Sustainable Development
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DOI：
10.1002/cssc.201600895
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发表时间：
2016-12-20
期刊：
影响因子：
8.4
通讯作者：
Pagliaro, Mario
中科院分区：
文献类型：
--
作者：
Ciriminna, Rosaria;Albanese, Lorenzo;Pagliaro, Mario
过氧化氢是一种在水和氧气中分解的绿色氧化剂，全球过氧化氢的使用量已从30年前的每年50万吨增加到2014年的每年450万吨，并且仍在攀升。为了扩大这种杰出的绿色化学品在不同工业和民用部门的利用，本文综述了过氧化氢作为绿色工业氧化剂的生产和使用，以提供其在过去三十年中工业用途的爆炸性增长和其工业制造的最新技术水平的概述，与传统的自氧化方法相比，是什么决定了由氧和氢直接生产的可行性的重要细节。
The global utilization of hydrogen peroxide, a green oxidant that decomposes in water and oxygen, has gone from 0.5 million tonnes per year three decades ago to 4.5 million tonnes per year in 2014, and is still climbing. With the aim of expanding the utilization of this eminent green chemical across different industrial and civil sectors, the production and use of hydrogen peroxide as a green industrial oxidant is reviewed herein to provide an overview of the explosive growth of its industrial use over the last three decades and of the state of the art in its industrial manufacture, with important details of what determines the viability of the direct production from oxygen and hydrogen compared with the traditional auto-oxidation process.