Polymer Compatibilization Through Hydrogen Bonding
Polymer Compatibilization Through Hydrogen Bonding
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DOI：
10.1080/00222338408056598
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发表时间：
1984-07
期刊：
影响因子：
--
通讯作者：
E. Pearce;T. Kwei;B. Min
中科院分区：
文献类型：
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作者：
E. Pearce;T. Kwei;B. Min
含乙烯基苯基六氟二甲基甲醇的部分改性聚苯乙烯与一些含聚苯乙烯的反聚物共混，聚醋酸乙烯酯（甲基丙烯酸甲酯），聚甲基丙烯酸乙酯、聚甲基丙烯酸正丁酯、聚（乙烯基甲基醚），聚（2，6二甲基-1，4苯醚），双酚A聚碳酸酯聚（苯乙烯-共-丙烯腈-腈）、聚（二甲基硅氧烷）、可结晶聚酯、无定形聚酰胺和两种无定形聚酰胺。氢键的相互作用，以影响可溶解性有关的改性聚苯乙烯中的质子供体基团的数量，这些方面进行了研究，较低的临界溶液温度和氢键的共混物的玻璃化转变温度。
Abstract Partially modified polystyrene containing vinyl phenyl hexafluorodimethyl carbinol was mixed with a number of counterpolymers containing poly(vinyl-acetate), poly(methyl methacry1 ate), poly(ethy] methacrylate, poly (n-butyl methacry late), poly(viny] methyl ether), poly(2,6 dimethyl-1,4 phenylene oxide), bisphenol A polycarbonate poly(styrene-co-acryloni-trile), poly (dimethyl siloxane), a crystallizable polyester, an amorphous polyamide and two amorphous polyamides. Hydrogen bonding interactions to effect miscibility were related to the number of proton donating groups in the modified polystyrene, and these were studied in regard to lower critical solution temperatures and the glass transition temperatures of the hydrogen bonded blends.