Taming salophen in rare earth metallocene chemistry
Taming salophen in rare earth metallocene chemistry
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DOI：
10.1039/d1qi01331a
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发表时间：
2022
影响因子：
7
通讯作者：
E. Castellanos;Florian Benner;Selvan Demir
中科院分区：
文献类型：
--
作者：
E. Castellanos;Florian Benner;Selvan Demir
首次合成了一系列以水杨酚为桥连的稀土异戊烯化合物（Cp ~*~ 2 RE）~ 2（μ-tBusalophen）（RE = Gd，Dy，Y）。固体和溶液状态已明确其特征在于磁性，光谱和DFT方法。
An unprecedented series of salophen-bridged rare earth metallocenes, (Cp*2RE)2(μ-tBusalophen) (RE = Gd, Dy, and Y), has been crystallized. The solid and solution states have been unambiguously characterized by magnetic, spectroscopic and DFT methods.