Chirality in Supramolecular Assemblies: causes and consequences
Chirality in Supramolecular Assemblies: causes and consequences
复制标题
超分子组装中的手性：原因和后果
DOI：
10.1002/9781118867334
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发表时间：
2016
影响因子：
2.5
通讯作者：
F. Keene
中科院分区：
文献类型：
--
作者：
F. Keene
[Back超分子化学涉及使用非共价相互作用将分子组织成定义的组装体，包括较弱和可逆的相互作用，如氢键和金属配体相互作用。在这种化学结构中的立体化学方面，特别是手性，是特别感兴趣的，因为它影响分子识别，功能材料的开发，同手性的棘手问题，界面相互作用的纳米级效应，生物催化和酶催化，以及在有机合成中的应用。手性在超分子组装地址许多这些方面，提出了广泛的概述这一重要的和迅速发展的跨学科领域。涵盖的主题包括：
分子和拓扑手性的起源
同手性发生
结晶度手性
主客体行为
功能材料中的手性影响
网络固体和配位固体中的手征性
界面手征性
有机组装体中的手性
手性与有机合成中的生物催化和酶
这本书是一个有价值的参考研究人员在分子科学，材料科学和生物科学工作与手性超分子系统。它提供了各个领域公认的国际专家的摘要和特别见解。
[Back Cover] Supramolecular chemistry deals with the organisation of molecules into defined assemblies using non-covalent interactions, including weaker and reversible interactions such as hydrogen bonds, and metal-ligand interactions. The aspect of stereochemistry within such chemical architectures, and in particular chirality, is of special interest as it impacts on considerations of molecular recognition, the development of functional materials, the vexed question of homochirality, nanoscale effects of interactions at interfaces, biocatalysis and enzymatic catalysis, and applications in organic synthesis. Chirality in Supramolecular Assemblies addresses many of these aspects, presenting a broad overview of this important and rapidly developing interdisciplinary field. Topics covered include:
Origins of molecular and topological chirality
Homochirogenesis
Chirality in crystallinity
Host-guest behavior
Chiral influences in functional materials
Chirality in network solids and coordination solids
Aspects of chirality at interfaces
Chirality in organic assemblies
Chirality related to biocatalysis and enzymes in organic synthesis
This book is a valuable reference for researchers in the molecular sciences, materials science and biological science working with chiral supramolecular systems. It provides summaries and special insights by acknowledged international experts in the various fields.