An achiral form of the hexameric resorcin[4]arene capsule sustained by hydrogen bonding with alcohols.

An achiral form of the hexameric resorcin[4]arene capsule sustained by hydrogen bonding with alcohols.
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DOI:
10.1039/b604148e
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发表时间:
2006-05
影响因子:
4.9
通讯作者:
Onome Ugono;K. Travis Holman
Onome Ugono;K. Travis Holman
中科院分区:
化学2区
文献类型:
--
作者:
Onome Ugono;K. Travis Holman

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通过间苯二酚[4]芳烃1与水分子的自组装维持的众所周知的六聚体胶囊(1(6).(H2O)8)与(+/-)-2-乙基己醇(2 EH)类似地组装为非手性1(6)。(2EH)6.(H2O)2物质,其进一步包封2 EH。
The well-known hexameric capsules sustained by self-assembly of resorcin[4]arenes 1 with water molecules (1(6).(H2O)8) are shown to assemble similarly with (+/-)-2-ethylhexanol (2EH) as an achiral 1(6).(2EH)6.(H2O)2 species which further encapsulates 2EH.