A highly transparent and luminescent hybrid based on the copolymerization of surfactant-encapsulated polyoxometalate and methyl methacrylate
A highly transparent and luminescent hybrid based on the copolymerization of surfactant-encapsulated polyoxometalate and methyl methacrylate
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DOI：
10.1002/adma.200500893
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发表时间：
2005-11-18
影响因子：
29.4
通讯作者：
Wu, LX
中科院分区：
文献类型：
--
作者：
Li, HL;Qi, W;Wu, LX
由端不饱和表面活性剂包封的聚金属氧酸盐和甲基丙烯酸甲酯共聚制备了一种多金属氧酸盐基杂化物。这种杂化物具有柔性可加工性、聚合物的高透明度和无机簇的高荧光性（见图）。本文提出的方法为在聚合物基体中制备有机-无机静电复合物基材料提供了一般途径。
A polyoxometalate-based hybrid is produced by the copolymerization of a terminal-unsaturated surfactant-encapsulated polyoxometalate and methyl methacrylate. This hybrid exhibits flexible processability, high transparency of the polymer, and high fluorescence of the inorganic cluster (see Figure). The method presented in this paper provides general access to the fabrication of organic-inorganic electrostatic-complex-based materials in polymer matrices.