Repeatability and reproducibility of retention data and band profiles on six batches of monolithic columns
Repeatability and reproducibility of retention data and band profiles on six batches of monolithic columns
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DOI：
10.1016/s0021-9673(01)01227-4
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发表时间：
2002-06-25
影响因子：
4.1
通讯作者：
Guiochon, G
中科院分区：
文献类型：
--
作者：
Kele, M;Guiochon, G
在来自Merck的一系列六个Chromolith Performance柱上，在五组不同的实验条件下，针对总共30种中性、酸性和碱性测试化合物，获得八种不同混合物的色谱数据。这些柱由C-18化学键合的二氧化硅整料制成。每个色谱柱属于不同的生产批次，因此此处报告的数据表征了其批次间的重现性。在这项工作中研究的参数是保留时间，保留和分离因子，疏水和空间选择性，柱效率，和所有30种化合物的拖尾因子。(C)2002 Elsevier Science B. V.保留所有权利。
Chromatographic data were acquired for eight different mixtures, under five different sets of experimental conditions, for a total of 30 neutral, acidic and basic test compounds, on a series of six Chromolith Performance columns from Merck. These columns are made of a C-18 chemically bonded silica monolith. Each column belonged to a different production batch, so the data reported here characterize their batch-to-batch reproducibility. The parameters studied in this work were the retention times, the retention and separation factors, the hydrophobic and the steric selectivities, the column efficiencies, and the tailing factors for all 30 compounds. (C) 2002 Elsevier Science B.V. All rights reserved.