STABILIZATION OF MONONUCLEAR PALLADIUM(III) - THE SINGLE-CRYSTAL X-RAY STRUCTURE OF THE [PD(L)2]3+ CATION (L=1,4,7-TRITHIACYCLONONANE)
STABILIZATION OF MONONUCLEAR PALLADIUM(III) - THE SINGLE-CRYSTAL X-RAY STRUCTURE OF THE [PD(L)2]3+ CATION (L=1,4,7-TRITHIACYCLONONANE)
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DOI：
10.1039/c39870000987
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发表时间：
1987-07-01
影响因子：
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通讯作者：
SCHRODER, M
中科院分区：
文献类型：
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作者：
BLAKE, AJ;HOLDER, AJ;SCHRODER, M
绿色[Pd(1)2]2+阳离子[(1)= 1,4,7-三thiacyclonane]在70% HClO4水溶液中氧化得到红色[Pd(1)2]3+阳离子，其单晶x射线结构显示Pd - s (1) 2.5448(15), Pd - s(4) 2.3558（14）和Pd - s (7) 2.3692（15）Å在PdIII中心的四边形扭曲几何。
Oxidation of the green [Pd(1)2]2+ cation [(1)= 1,4,7-trithiacyclononane] in 70% aqueous HClO4 affords the red [Pd(1)2]3+ cation, the single crystal X-ray structure of which shows a tetragonally distorted geometry about the PdIII centre with Pd–S(1) 2.5448(15), Pd–S(4) 2.3558(14), and Pd–S(7) 2.3692(15)Å.